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Fractional Revivals in the ro-vibrational motion of I2

Motivated by pump–probe experiments of I2 in a room-temperature sample, the detection of fractional revivals is investigated using full-dimensional quantum wave packet calculations. It is shown that the structures observed in the pump–probe signal depend sensitively on the probe parameters employed and that the observed signal reflects a particular phase effect between fractional revivals.

Voir en ligne : J. Chem. Phys. 120, 10442-10449 (2004)