Université Paul Sabatier - Bat. 3R1b4 - 118 route de Narbonne 31062 Toulouse Cedex 09, France


Home > Publications > Publications by year > Year 2004

Fractional Revivals in the ro-vibrational motion of I2

Motivated by pump–probe experiments of I2 in a room-temperature sample, the detection of fractional revivals is investigated using full-dimensional quantum wave packet calculations. It is shown that the structures observed in the pump–probe signal depend sensitively on the probe parameters employed and that the observed signal reflects a particular phase effect between fractional revivals.

View online : J. Chem. Phys. 120, 10442-10449 (2004)